The first teamer dominated the game and scoresheet as Spurs won 9-1 on the day.
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Teammate Tynan Thompson also scored a hat-trick for Spurs, with talented defender James Rowswell also finding the net.
Williams-Barnett, 17, featured in the Carabao Cup this season for Spurs and confirmed his growing reputation with this performance.
The victory marks Tottenham's biggest win in the competition, surpassing their 9-2 thrashing of Red Star Belgrade in 2019.