Baldini, the current Italy U21 coach, will take charge for the Azzurri's two friendlies against Luxembourg and Greece in June.
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He steps up after Rino Gattuso resigned last week following Italy's World Cup qualifying playoff defeat to Bosnia.
FIGC announced today: "The national team will return to action in just under two months, facing Luxembourg on Wednesday, June 3rd (8:45 p.m.) at the Stade de Luxembourg, and on Sunday, June 7th (8:45 p.m.) at the Pankritio Stadium in Heraklion, Crete, for another friendly against Greece.
"Under-21 national team coach Silvio Baldini will lead the Azzurri in both matches, assisted by his staff."
Baldini, 67, is a former coach of Empoli and Palermo among several clubs.