Donley moves to Oxford on-loan to June with an option to buy.
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The attacker was with Stoke City over the first-half of the season before being recalled this week and being sent to the Kassam Stadium.
"I want to influence games and be decisive in the final third, but that all starts with hard work. I take real pride in working for the team and doing the basics right," Donley told the club website.
"My loan experiences have taught me a lot. I've had big highs and challenging moments but those are what shape you as a player. I feel ready to come here, compete, and show what I can bring"
Donley is eligible to make his U's debut in their next Championship match against Sheffield United on Sunday.