Pimienta succeeds Quique Sanchez Flores, who stepped down after guiding Sevilla away from relegation danger.
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He moves from Las Palmas to Sevilla and will sign a two-year contract.
Sevilla announced the appointment of Pimienta on Sunday.
He arrives in Nervin with David Gomez (physical trainer), Alex Garca (assistant coach) and Albert Peris (technical assistant).