PSG have announced the Spaniard, 55, suffered a fractured collarbone in the accident.
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"The club expresses its full support and wishes him a swift recovery. Further updates will be shared in due course," PSG said.
For the moment, there is no news regarding Enrique's recovery period.
After the international break, PSG will face Lens on 14 September in their next league fixture before they begin their Champions League defence against Atalanta in the league phase three days later.